Bio-Inspired 3d-Printed Microstructures For Toughening Bio-Based Epoxy Matrix

Abstract

Aiming to aid the sustainable transition to fossil fuel-free epoxy materials and enhance the toughness of bio-based epoxies, here we integrate an overlapping curl microstructure consisting of coiling fiber with sacrificial bonds and hidden lengths into a bio-based epoxy matrix. Inspired by natural material, where exceptional properties are achieved at low environmental cost, the microstructure mimics the molecular structures of spider silk, known for its exceptional fracture resistance. The 3D-printed overlapping curl shows a saw-tooth mechanical response with continuous load-carrying ability thanks to the break of sacrificial bonds and unfolding of the hidden lengths. By embedding the overlapping curl into the compact-tension configuration of the bio-based epoxy, an extrinsic toughening mechanism is triggered as the hidden length unfolds. Experimental results show that a single-sided overlapping curl structure is able to improve the toughness of bio-based epoxy by 19%.

Publication
Proceedings of the 21st European Conference on Composite Materials
Zhiyuan Xu
Zhiyuan Xu
PhD Candidate

My research interests in 3D printing and bio-inspired toughening designs.

Ran Tao
Ran Tao
Postdoc Researcher

My research interests in 3D printing and bio-inspired toughening designs.

Sofia Teixeira de Freitas
Sofia Teixeira de Freitas
Principal Investigator

Sofia Teixeira de Freitas researches the structural integrity of bonded and layered materials to enable durable, sustainable structures. She is also an accredited group facilitator, committed to building academic environments grounded in cooperation and inclusion—key to overcoming technological limits and addressing the challenges of a truly sustainable society.